Arriving in Guangzhou from Melbourne,leaving 0815 hour to Urumqi then fly off to Almaty at 2030 hour

I arriving in Guangzhou at 0600 hours from Melbourne, leaving 0815 hours to Urumqi then fly off to Almaty in Kazakhstan in 2030 hours. Can I can get TWOV in Guangzhou and uses the visa waiver to fly domestically to Urumqi ?
Sorry forgotten to mention that I am travelling with a same airline in all the three connecting flights.. Thank you