I have an invitation for m.s.c in peaking university china.

Israt, if you will apply for the student X1 type, your husband can apply for an S1 type to PRC with you. You need to prepare those documents to apply for the S1 type for him: his passport and its copy, the application form, a passport-style photo, an invitation letter from the school, an invitation letter from you, and your marriage certificate. And then submit the application to the embassy of PRC along with the application for your student X1 type.