Spanish citizen to arrive in Chengdu International Airport to perform on Chengdu Youth International

Can a Spanish citizen to arrive in Chengdu International Airport to perform on Chengdu Youth International apply for a visa on arrival? The problem is that the passport was issuing was too long and in addition to that, it may not be picked up until 15 July, while she has to leave on 19 July and there are no 24-hour rush services in Spain.