What time the last operating of subway (Baiyun Line) and what time began operation in the morning ?

For the Baiyun Line, I think you may mean the subway line 3 that reach the Baiyun airport, right?
If so, the last train is around 23:00, so you cannot take that line.
I think you may need to take the airport express line 1 to reach its terminal at the Civil Aviation Ticket Office and then change to take a taxi to reach your hotel directly.