Do you mean from Xucheng of Henan Province to Zhejiang? If so, I'm afraind that there is no direct train or flight from Xuchang to Zhejiang, such as Hangzhou. So, you have to transfer at the third station. Or, you could consider fly to Hangzhou from Zhengzhou & Luoyang in Henan or even Xi'an of Shaanxi.
Just for your reference!